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What would be the pH of an aqueous solution of sulphuric acid which is 5\times10^{–5} mol litre^{–1} in concentration?
Sulphuric acid dissociates in water as:
Each mole of sulphuric acid gives of H^+ ions in the solution. One litre of H_2SO_4 solution contains 5\times10^{–5} moles of H_2SO_4 which would give
2×5×10^{–5}=10×10^{–5} or
1.0×10^{–4} moles of H^+ ion in one litre of the solution.
Therefore,
[H^+]=1.0×10^{–4} mol litre^{–1}
pH=–log_{10}[H^+]
= –log_{10}10^{–4}